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This booklet is a comprehensive resource for first-year LMD students in Science and Technology (ST) and Material Science (SM), focusing on the fundamental concepts of electrostatics. It includes a clear and concise reminder of the course as well as detailed solutions to carefully selected exercises, enabling students to deepen their understanding. The document covers the basics of electric charges, Coulomb's law, electric field and potential, the principle of superposition, and Gauss's law. Practical examples illustrate the applications of charge distributions and conductor properties. Exercises cover topics such as electrostatic force, electric fields and flux calculations, reinforcing theoretical knowledge. By combining concise theory with practical applications, this booklet provides a solid foundation for exploring electromagnetism and related fields.